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If it's an activated ability, you can use that ability at any time as long as the case remains solved

Resource Management Managing energy cards, items, and Pokmon on the battlefield teaches resource management

Why is this scenario last

The card also has a whopping 170 HP, giving it enough endurance to easily see out the battle

While Irida healing for 40 can certainly help Palkia slug it out in a prolonged fight, overall the deck just seems like a worse version of the two-Articuno strategy (indeed its one loss was against just such a deck).So we're wondering, did the Palkia deck's pilot, TheSuperTNT, just get really lucky with those Misty coin flips